Petroleum Process and Product Analysis
Petrochemical Product Analysis
Petrochemical Product Analysis
炼油厂和饼干操作变得更加复杂，利润更紧密，需要重新关注过程控制，原料分析和产品质量控制。石油组成的高级分析使操作员能够更有利地优化炼油厂运营。此外，扩大燃料的监管控制需要可靠且易于使用的常规分析。Bruker致力于下游和石化片段，具有专门的解决方案和专业知识，可实施新的或改进的工作流程。布鲁克（Bruker）提供了to Solutionswe，是您在石化产品分析和过程控制解决方案中的合作伙伴。
FT-NIR
FT-NIR in Fuel & Analysis
Gasoline, Diesel and Jet fuels require extensive testing in the laboratory for process optimization, blend optimization and efficiency and to reduce the instance of octane giveaway. Previously, this required many independent tests including simulated distillation, GC and Knock Engine Testing. New advances in Fourier Transform Near Infrared spectroscopy now mean that multiple chemical and& physical properties can be derived from one sample/one spectrum in seconds. Properties include:
- 罗恩，蒙，庞
- RVP, T5, T10, T50, T90, T95, IBP, FBP
- 苯，芳香族剂，烯烃，饱和
r力量开发了独特的解决方案efinery fuels laboratories which includes calibrations developed using many thousands of fuel samples.
分子分类
Petroleomics: The Molecular Classification of Petroleum
在石油工业中，对原油和原油分数的确切化学成分的详细知识。具有相似甚至相同体积化学特性的原油可能完全不同。示例包括在炼油过程中反应不同，其中特定的化合物和化合物可能会导致催化失活。
Flow assurance interests are with polar compounds in crude oil containing hetero atoms such as nitrogen, sulfur and oxygen having a high contribution in deposition and clogging of pipelines. Even in oil exploration, the exact chemical class information can be useful for reservoir connectivity studies.
因此，有关这些有问题的复合类相对丰度的详细信息引起了人们的重大兴趣。
化合物类别的相对丰度，以及基于环和双键等效物的类别的详细核心结构信息，可以通过超高分辨率质谱来得出。
可以使用不同的电离方法（APPI，ESI，LDI）在几分钟内无需任何样品纯化即可分析原油。然后使用高级软件解决方案（Petroorg/Composer）处理质谱数据。
Elemental Classification
Explore XRF Solutions for Petrochemical Standards
Elemental analysis is a crucial process control tool for the refining process: XRF is employed as a technique to quantify sulfur from the crude oil to the liquid streams and in the refined products as well as to quantify Ni, Fe and V in crude oils.: Since XRF can analyze the sample directly without digestion or dilution it is the technique that is widely employed as process tool.: Sulfur levels in fuels are regulated, compliance analysis can be performed with XRF by applying ASTM, ISO or other national norms such as ASTM D2622. Residual fuel oils as well as solid petcoke can be analyzed as well directly.
For the lowest detection limits, as well as for testing P, Pb , S,Ni,V and many more elements in a laboratory setting theS8 TIGER Series 2 WDXRFunits are used by many refineries.
较小的炼油厂以及可以使用EDXRF（例如ISO 13032，ASTM D7220和D4294）来完成硫和超低硫的调节性的区域。S2极性with factory calibrated solutions.
IMO 2020 Low Sulfur in Fuel Regulations
国际预防船舶污染（MARPOL）禁止对不合规燃料油的污染公约于2020年3月1日生效。Quickly and accurately measure sulfur in marine fuels to ensure bunker fuels meet regulations in Emission Control Areas and other restricted locations. This method follows ASTM D4294 higher concentration range of 0.1 to 5.0% Sulfur in Fuel and ISO 8754:2003. Suppliers, engineers, ship captains and inspectors can use our portable XRF Sulfur Measurement solutions at service labs, supply stations, on docks, in ports, and even aboard barges and ships.
布鲁克’s CTX portable XRF system provides a reliable and inexpensive verification of sulfur in fuel onboard or at the terminal.
TD-NMR
TD-NMR烃分析
时域核磁共振（TD-NMR），也称为低分辨率NMR，是用于石油和工艺分析的负担得起的NMR解决方案。磁场松弛时间可用于确定物理和化学特性，包括：
原油分析
- 粘度
- Droplet size distribution (oil-in-water, water-in-oil)
- 氢含量
Distillation Monitoring
- % Hydrogen in seconds (ASTM techniques)
- 自动裂缝过程控制
油砂分离
- Real-time monitoring of bitumen, water, solvents in separation samples
- 样本尺寸：毫克至1000克
- No sample preparation necessary
- 颜色，不透明度不会影响测量
- Simple and short calibration procedure
NMR
NMR for Fuel Analysis
NMR has found application in the fuel industry since its inception as a commercial product, and the fuel additives field has since become a heavily studied area of the industry. Often, fuel companies will carry out this research themselves and use NMR to acquire detailed information on the chemical makeup of raw petroleum.
